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$^{1}_{\infty}\rm [Li_{3}(NbSe_{4})\cdot4MeCN]$ – ein neues lösliches Tetrachalkogenoniobat
Author(s) -
Feuerhake Robert,
Sahin Hülya,
Fenske Dieter
Publication year - 2005
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200500098
Subject(s) - phosphine , acetonitrile , reactivity (psychology) , chemistry , crystallography , crystal structure , single crystal , copper , polar , stereochemistry , medicinal chemistry , organic chemistry , physics , catalysis , medicine , alternative medicine , pathology , astronomy
$^{1}_{\infty}\rm [Li_{3}(NbSe_{4})\cdot4MeCN]$ – a Novel Soluble Tetrachalcogenoniobate In Acetonitrile, Nb(OEt) 5 reacts with LiOMe and Se(SiMe 3 ) 2 to form the novel tetraselenoniobate $^{1}_{\infty}\rm [Li_{3}(NbSe_{4})\cdot4MeCN]$ . The molecular structure was determined by single crystal X‐ray diffraction. The new compound is soluble in polar organic solvents and seems to be a suitable starting material for the synthesis of new heterobimetallic complexes, as some reactivity towards copper phosphine complexes could be observed.