Premium
Chemischer Transport fester Lösungen. 18 [1] Der Chemische Transport von ZnIn 2 S 4 , ZnIn 2 Se 4 und ZnIn 2 S 4−x Se x ‐Mischphasen
Author(s) -
Locmelis S.,
Milke E.,
Binnewies M.,
Gruhl S.,
Vogt C.
Publication year - 2005
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200500038
Subject(s) - chemistry , mass transport , analytical chemistry (journal) , physics , chromatography , engineering physics
Chemical Vapor Transport of Solid Solutions. 18. [1] Chemical Vapor Transport of ZnIn 2 S 4 , ZnIn 2 Se 4 and ZnIn 2 S 4−x Se x ‐mixed Crystals By means of CVT methods using iodine as transport agent (725 → 675 °C) ZnIn 2 S 4 , ZnIn 2 Se 4 und ZnIn 2 S 4−x Se x ‐mixed phases could be obtained. Mass spectrometric investigations show the formation of ZnI 2 (g) and InI 3 (g) are due to the transport reaction. The transport process leads to a significant enrichment of sulphur.