A Coordination Polymer from HAMTTO with Silver(I) (HAMTTO = 4‐Amino‐6‐methyl‐1,2,4‐triazine‐3‐thione‐5‐one) | Zendy

Ghassemzadeh Mitra | Zendy; Adhami Forough | Zendy; Taeb Abas | Zendy; Heravi Majid M. | Zendy; Neumüller Bernhard | Zendy

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A Coordination Polymer from HAMTTO with Silver(I) (HAMTTO = 4‐Amino‐6‐methyl‐1,2,4‐triazine‐3‐thione‐5‐one)

Author(s) -

Ghassemzadeh Mitra,

Adhami Forough,

Taeb Abas,

Heravi Majid M.,

Neumüller Bernhard

Publication year - 2005

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200500036

Subject(s) - chemistry , deprotonation , denticity , ligand (biochemistry) , coordination polymer , triazine , crystal structure , methanol , hydrazine (antidepressant) , medicinal chemistry , chelation , infrared spectroscopy , silver nitrate , polymer chemistry , inorganic chemistry , crystallography , nuclear chemistry , organic chemistry , ion , biochemistry , receptor , chromatography

The reaction of 4‐amino‐6‐methyl‐1,2,4‐triazine‐3‐thione‐5‐one, HAMTTO, with silver (I) nitrate in methanol led under deprotonation to the polymeric compound [(AMTTO)Ag] n . The coordination polymer {[Ag(HAMTTO)]ClO 4 } n ( 1 ) is synthesized from the reaction of the latter polymeric compound with perchloric acid. Both compounds were characterized by elemental analysis and IR spectroscopy. Single‐crystal X‐ray diffraction studies on compound 1 showed that HAMTTO acts as a bidentate ligand and chelates the silver atom via its hydrazine nitrogen atom and its sulfur atom. Crystal data for 1 at −90 °C: space group P2 1 , Z = 2, a = 629.3(1), b = 748.7(1), c = 1071.7(1) pm, β = 98.28(1)°, R 1 = 0.0533.

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