Synthesis, Characterization and Crystal Structure of Dimeric {[(AMTTO) 2 Ag]NO 3 } 2  (AMTTO = 4‐Amino‐6‐methyl‐1, 2, 4‐triazine‐3(2H)‐thione‐5‐one) | Zendy

Ghassemzadeh Mitra | Zendy; Tabatabaee Masomeh | Zendy; Mirrokni Zohreh | Zendy; Neumüller Bernhard | Zendy

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Synthesis, Characterization and Crystal Structure of Dimeric {[(AMTTO) 2 Ag]NO 3 } 2 (AMTTO = 4‐Amino‐6‐methyl‐1, 2, 4‐triazine‐3(2H)‐thione‐5‐one)

Author(s) -

Ghassemzadeh Mitra,

Tabatabaee Masomeh,

Mirrokni Zohreh,

Neumüller Bernhard

Publication year - 2005

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200500012

Subject(s) - orthorhombic crystal system , crystal structure , crystallography , chemistry , methanol , coordination sphere , triazine , elemental analysis , crystal (programming language) , infrared spectroscopy , solid state , spectroscopy , stereochemistry , inorganic chemistry , physics , organic chemistry , computer science , programming language , quantum mechanics

The reaction of 4‐Amino‐6‐methyl‐1, 2, 4‐triazine‐3(2H)‐thione‐5‐one (AMTTO, 1 ) with silver nitrate in methanol led to the dimeric complex {[(AMTTO) 2 Ag]NO 3 } 2 ( 2 ). 2 was characterized by elemental analyses and IR spectroscopy as well as by X‐ray structure analysis. Crystal data for 2 at −80 °C: crystal system orthorhombic, space group P2 1 2 1 2 1 with a = 1043.6(1), b = 1329.6(1), c = 2358.4(1) pm, Z = 8 and R 1 = 0.037. The cation possesses a highly distorted linear coordination sphere in the solid state.

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