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Synthesis of a Stable Biphenyl‐Bis(carbene) and ‐Bis(silylene) [M{(NCH 2 Bu t ) 2 C 6 H 3 ‐3,4}] 2 (M = C or Si)
Author(s) -
Gehrhus Barbara,
Hitchcock Peter B.,
Lappert Michael F.
Publication year - 2005
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200500005
Subject(s) - silylene , carbene , biphenyl , chemistry , medicinal chemistry , derivative (finance) , stereochemistry , crystallography , silicon , organic chemistry , catalysis , financial economics , economics
Treatment of the biphenyl derivative [S=C{(NCH 2 Bu t ) 2 C 6 H 3 ‐3,4}] 2 or [Cl 2 Si{(NCH 2 Bu t ) 2 C 6 H 3 ‐3,4}] 2 with C 8 K afforded the new bis(carbene) 1 or the first bis(silylene) 2 , respectively. The X‐ray structure of 2 is presented.