A Chiral Amide Derivative with the β‐P 4 S 3  Cage Skeleton | Zendy

Tattershall Bruce W. | Zendy; Booth Claire L. | Zendy

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A Chiral Amide Derivative with the β‐P 4 S 3 Cage Skeleton

Author(s) -

Tattershall Bruce W.,

Booth Claire L.

Publication year - 2005

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200500001

Subject(s) - diastereomer , chirality (physics) , amide , skeleton (computer programming) , derivative (finance) , chemistry , stereochemistry , cage , axial chirality , crystallography , combinatorics , enantioselective synthesis , chiral symmetry , organic chemistry , mathematics , catalysis , physics , computer science , quantum mechanics , financial economics , nambu–jona lasinio model , economics , programming language , quark

The diamide exo, exo ‐ β ‐P 4 S 3 (NHCH(Me)Ph) 2 has been made in solution using enantiomerically pure or racemic PhCH(Me)NH 2 , and its three diastereomers characterised by complete analysis of their 31 P{ 1 H} NMR spectra.The unsymmetric diastereomer contains phosphorus atoms, made chemically non‐equivalent by the chirality of the substituents, which show a large 2 J (P—P—P) coupling to each other (225.2 Hz).

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