Synthesis and Characterization of New Copper(I) Complexes Containing Thione Derivatives of 1, 2, 4‐Triazine. Crystal Structure of [Cu(PPh 3 ) 2 (ATTO)]NO 3  (ATTO = 4‐amino‐1, 2, 4‐triazin‐3(2H)‐thione‐5‐one) | Zendy

Yazdanbakhsh Mohammad | Zendy; Hakimi Mohammad | Zendy; Heravi Majid M. | Zendy; Ghassemzadeh Mitra | Zendy; Neumüller Bernhard | Zendy

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Synthesis and Characterization of New Copper(I) Complexes Containing Thione Derivatives of 1, 2, 4‐Triazine. Crystal Structure of [Cu(PPh 3 ) 2 (ATTO)]NO 3 (ATTO = 4‐amino‐1, 2, 4‐triazin‐3(2H)‐thione‐5‐one)

Author(s) -

Yazdanbakhsh Mohammad,

Hakimi Mohammad,

Heravi Majid M.,

Ghassemzadeh Mitra,

Neumüller Bernhard

Publication year - 2004

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200480012

Subject(s) - denticity , crystallography , raman spectroscopy , chemistry , ligand (biochemistry) , single crystal , crystal structure , triazine , copper , crystal (programming language) , stereochemistry , polymer chemistry , organic chemistry , physics , biochemistry , receptor , programming language , computer science , optics

The reaction of 4‐amino‐1, 2, 4‐triazin‐3(2H)‐thione‐5‐one (ATTO, 1 ) with [Cu(PPh 3 ) 2 ]NO 3 in ethanol led to the complex [Cu(PPh 3 ) 2 (ATTO)]NO 3 ( 2 ). 2 was characterized by elemental analyses, IR, 1 H NMR and Raman spectroscopy. A single‐crystal X‐ray diffraction of compound 2 revealed that ATTO acts as a bidentate ligand via its nitrogen and sulfur atoms. Crystal data for 2 at 20 °C: space group P2 1 /n with a = 975.7(1), b = 1533.5(2), c = 2504.2(3) pm, β = 92.25(1)°, Z = 4, R 1 = 0.0632.

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