[Hg 2 ( μ ‐bpe)( μ ‐OAc) 2 ( μ ‐SCN) 2 ] n , a New Two‐Dimensional Coordination Polymer Involving Three Simultaneously Bridging Ligands: 1,2‐Bis(4‐pyridyle)ethene, Acetate, and Thiocyanate | Zendy

Morsali Ali | Zendy; Yilmaz Veysel T. | Zendy; Kazak Canan | Zendy

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[Hg 2 ( μ ‐bpe)( μ ‐OAc) 2 ( μ ‐SCN) 2 ] n , a New Two‐Dimensional Coordination Polymer Involving Three Simultaneously Bridging Ligands: 1,2‐Bis(4‐pyridyle)ethene, Acetate, and Thiocyanate

Author(s) -

Morsali Ali,

Yilmaz Veysel T.,

Kazak Canan

Publication year - 2005

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200400550

Subject(s) - thiocyanate , crystallography , chemistry , stacking , infrared spectroscopy , polymer , coordination polymer , nuclear magnetic resonance spectroscopy , stereochemistry , crystal structure , inorganic chemistry , organic chemistry

A new mercury(II) complex of 1,2‐bis(4‐pyridyle)ethene (bpe) with anionic acetate and thiocyanate ligands has been synthesized and characterized by elemental analysis, IR, 1 H NMR and 13 C NMR spectroscopy. The single crystal X‐ray analysis shows that the complex is a two‐dimensional polymer with simultaneously bridging 1,2‐bis(4‐pyridyle)ethane, acetate and thiocyanate ligands and basic repeating dimeric [Hg 2 (μ‐bpe)(μ‐OAc) 2 (μ‐SCN) 2 ] units. The two‐dimensional system forms a three‐dimensional network by packing via π ‐ π stacking interactions.

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