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Silver‐Hydrogen Interactions in Crystalline Silver Dodecahydrododecaborates
Author(s) -
Volkov Oleg,
Hu Chunhua,
Paetzold Peter
Publication year - 2005
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200400518
Subject(s) - acetonitrile , acetone , hydrogen bond , chemistry , crystallography , hydrogen , stereochemistry , polymer chemistry , molecule , organic chemistry
The syntheses and structures of the three silver dodecahydrododecaborates: AmAgB 12 H 12 , Am(AgL) 2 Ag(B 12 H 12 ) 2 , and (AgL) 2 B 12 H 12 (Am = benzyltriethylammonium, NBzlEt 3 ; L = acetonitrile) are presented. The silver cations are connected to the B 12 H 12 2− cages by single or double hydrogen bonds to give chains, layers, or a three‐dimensional connection, respectively. For comparison, it is also reported on the syntheses and structures of the dodecabromododecaborates (AgL′) 2 B 12 Br 12 (L′ = acetone) and Am 2 B 12 Br 12 .