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Pb 2 (OH) 2 [ p ‐O 2 C‐C 6 H 4 ‐CO 2 ]: Synthese und Kristallstruktur
Author(s) -
Schuy Andrea,
Ruschewitz Uwe
Publication year - 2005
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200400485
Subject(s) - monoclinic crystal system , terephthalic acid , crystal structure , crystallography , hydrothermal synthesis , hydrothermal reaction , hydrothermal circulation , chemistry , stereochemistry , organic chemistry , seismology , polyester , geology
Pb 2 (OH) 2 [ p ‐O 2 C‐C 6 H 4 ‐CO 2 ]: Synthesis and Crystal Structure Single crystals of Pb 2 (OH) 2 [ p ‐O 2 C‐C 6 H 4 ‐CO 2 ] ( 1 ) were obtained by hydrothermal reaction of terephthalic acid and PbCO 3 at 180 °C (10 days). 1 crystallizes in the monoclinic space group P2 1 /c with Z = 2 (a = 1115.6(2) pm, b = 380.10(4) pm, c = 1141.3(2) pm, β = 93.39(1)°, V = 0.4831(1) nm 3 ). The crystal structure is characterized by ladder‐type Pb(OH) 3/3 double chains, which are connected to a three‐dimensional framework by terephthalate dianions.