The Structure of  cis ‐[Chloro(dimethylsulfoxide)bis(1, 10‐phenanthroline)ruthenium(II)]‐tetraphenylborate, [RuCl(DMSO)(1, 10‐phen) 2 ][BPh 4 ] | Zendy

Wu Biao | Zendy; Janiak Christoph | Zendy

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The Structure of cis ‐[Chloro(dimethylsulfoxide)bis(1, 10‐phenanthroline)ruthenium(II)]‐tetraphenylborate, [RuCl(DMSO)(1, 10‐phen) 2 ][BPh 4 ]

Author(s) -

Wu Biao,

Janiak Christoph

Publication year - 2005

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200400387

Subject(s) - ruthenium , monoclinic crystal system , phenanthroline , octahedron , chemistry , tetraphenylborate , bond length , crystallography , ligand (biochemistry) , stereochemistry , medicinal chemistry , crystal structure , ion , catalysis , biochemistry , receptor , organic chemistry

The complex cis ‐[RuCl(DMSO)(phen) 2 ]BPh 4 , where DMSO is dimethylsulfoxide and phen is 1, 10‐phenanthroline, crystallizes in the monoclinic space group P2 1 / c with a = 19.505(4), b = 10.045(2), c = 21.199(4) Å, β = 90.137(4)°, V = 4153(2) Å 3 , Z = 4, D calc = 1.430 g cm —3 . The ruthenium coordination geometry is that of a slightly distorted octahedron with a cis ‐RuN 4 ClS arrangement of the ligand donor atoms. The Ru—Cl distance is 2.421(1) Å and the Ru—S distance 2.250(2) Å. The four Ru—N distances are 2.057(6), 2.066(4), 2.073(4), and 2.086(4) Å with the Ru—N bond trans to Cl the second shortest and the Ru—N bond trans to S the longest one.

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