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Synthesis and Structural Characterization of a Novel Type of Heteropolyanion: [Sb 4 Mo 12 (OH) 6 O 48 ] 10‐
Author(s) -
Drewes Daniel,
Vollmer Guido,
Krebs Bernt
Publication year - 2004
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200400367
Subject(s) - antimony , raman spectroscopy , chemistry , crystallography , characterization (materials science) , oxygen atom , ion , spectroscopy , infrared spectroscopy , fluorescence , type (biology) , inorganic chemistry , molecule , materials science , nanotechnology , physics , organic chemistry , quantum mechanics , optics , ecology , biology
A novel antimony substituted polyoxomolybdate has been synthesized and characterized by X‐ray structure analysis, energy dispersive X‐ray fluorescence analysis, Raman and IR spectroscopy. The [Sb 4 Mo 12 (OH) 6 O 48 ] 10‐ anion exhibits a central Sb 4 (OH) 6 O 14 core where all Sb V atoms are coordinated octahedrally by six oxygen atoms. It represents a novel type of heteropolyanion with no known analogous structure in literature.