[Me 4 N] 5 [WOS 3 (CuCl) 3 Cl]Cl 2  ‐ a Cluster Compound with Alternating Anion Packing | Zendy

Dilshad R. | Zendy; Boller H. | Zendy; Klepp K. O. | Zendy

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[Me 4 N] 5 [WOS 3 (CuCl) 3 Cl]Cl 2 ‐ a Cluster Compound with Alternating Anion Packing

Author(s) -

Dilshad R.,

Boller H.,

Klepp K. O.

Publication year - 2004

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200400354

Subject(s) - crystallography , crystal structure , hexagonal crystal system , cluster (spacecraft) , ion , space group , diffraction , single crystal , chemistry , cubane , x ray crystallography , materials science , physics , optics , organic chemistry , computer science , programming language

Orange‐yellow plate‐like crystals of the title compound were obtained from the reaction of [Me 4 N] 2 WO 2 S 2 or [Me 4 N] 2 WOS 3 with CuCl and [Me 4 N]Cl in MeCN solution. They are hexagonal, space group P 6 3 cm (No.185), with unit cell parameters a = 11.638(4) Å, c = 17.970(7) Å, Z = 2. The crystal structure was determined from single crystal X‐ray diffraction data (MoKα‐radiation) and refined to R = 0.049. The structure is characterized as an alternating packing of cubane‐like [WOS 3 (CuCl) 3 Cl] 3‐ and Cl ‐ anions.

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