A Novel Polyoxovanadium Cluster Shell:  β ‐As 8 V 14 O 42 | Zendy

Zheng ShouTian | Zendy; Zhang Jie | Zendy; Yang GuoYu | Zendy

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A Novel Polyoxovanadium Cluster Shell: β ‐As 8 V 14 O 42

Author(s) -

Zheng ShouTian,

Zhang Jie,

Yang GuoYu

Publication year - 2005

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200400318

Subject(s) - orthorhombic crystal system , cluster (spacecraft) , crystallography , vanadium , crystal structure , hydrothermal circulation , chemistry , shell (structure) , hydrothermal synthesis , infrared spectroscopy , single crystal , materials science , inorganic chemistry , geology , organic chemistry , programming language , seismology , composite material , computer science

The hydrothermal reaction of VOSO 4 , As 2 O 5 , piperazine and H 2 O produces [H 2 N(CH 2 ) 4 NH 2 ] 4 [β‐As 8 V 14 O 42 (SO 4 )]·2HSO 4 ( 1 ), which is the first arsenic‐vanadium cluster containing a spherical β ‐As 8 V 14 O 42 shell. The structure of this compound was characterized by single crystal X‐ray diffraction, elemental analysis, TG, and IR spectrum. Crystal data for 1 : Orthorhombic, C mcm, a = 15.369(1) Å, b = 16.404(1) Å, c = 25.772(1) Å, V = 6497.4(9) Å 3 , Z = 4.

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