Formation, Structural Characterization, and Calculated NMR Chemical Shifts of Selenium‐Nitrogen Compounds from SeCl 4  and ArNHLi (Ar = supermesityl, mesityl) | Zendy

Maaninen Tiina | Zendy; Tuon Heikki M. | Zendy; Kosunen Katja | Zendy; Oilunkaniemi Raija | Zendy; Hiitola Johanna | Zendy; Laitinen Risto | Zendy; Chivers Tristram | Zendy

Premium

Formation, Structural Characterization, and Calculated NMR Chemical Shifts of Selenium‐Nitrogen Compounds from SeCl 4 and ArNHLi (Ar = supermesityl, mesityl)

Author(s) -

Maaninen Tiina,

Tuon Heikki M.,

Kosunen Katja,

Oilunkaniemi Raija,

Hiitola Johanna,

Laitinen Risto,

Chivers Tristram

Publication year - 2004

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200400286

Subject(s) - selenium , chemistry , molecule , crystallography , nuclear magnetic resonance spectroscopy , hydrogen bond , yield (engineering) , spectroscopy , crystal structure , diimide , stereochemistry , organic chemistry , materials science , physics , perylene , quantum mechanics , metallurgy

Supermesityl selenium diimide [Se{N(C 6 H 2 t Bu 3 ‐2, 4, 6)} 2 ; Se{N(mes*)} 2 ] can be prepared in a good yield from the reaction of SeCl 4 and (mes*)NHLi. The molecule adopts an unprecedented anti, anti ‐conformation, as deduced by DFT calculations at PBE0/TZVP level of theory and supported by 77 Se NMR spectroscopy and a crystal structure determination. An analogous reaction involving (C 6 H 2 Me 3 ‐2, 4, 6)NHLi [(mes)NHLi] unexpectedly lead to the reduction of selenium and afforded the selenium diamide Se{NH(mes)} 2 that was characterized by X‐ray crystallography and 77 Se NMR spectroscopy. The Se‐N bonds of 1.847(3) and 1.852(3) Å show normal single bond lengths. The

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research