Allylic Peroxidations with Bis(2‐pyridylimino)isoindolato‐Cobalt and ‐Iron Complexes | Zendy

Meder Markus B. | Zendy; Siggelkow Bettina A. | Zendy; Gade Lutz H. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Allylic Peroxidations with Bis(2‐pyridylimino)isoindolato‐Cobalt and ‐Iron Complexes

Author(s) -

Meder Markus B.,

Siggelkow Bettina A.,

Gade Lutz H.

Publication year - 2004

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200400253

Subject(s) - allylic rearrangement , cobalt , chemistry , isoindole , cyclohexene , aqueous solution , medicinal chemistry , catalysis , molar ratio , metal , polymer chemistry , nuclear chemistry , inorganic chemistry , organic chemistry

Several novel substituted bis(2‐pyridylimino)isoindolato (BPI) cobalt(II) and iron(II) complexes [M(BPI)(OAc)(H 2 O)] (M = Co: 1 ‐ 6, Fe: 7) have been synthesized by reaction of bis(2‐pyridylimino)isoindole derivatives with the corresponding metal(II) acetates. Reaction of 1‐6 with 1.5 ‐ 2 molar equivalents of t ‐BuOOH gave the corresponding alkylperoxocobalt(III) complexes [Co(BPI)(OAc)(OO t Bu)] (10 ‐ 15). Using an aqueous solution of t ‐BuOOH (70 %), cyclohexene was selectively catalytically oxidized to the dialkylperoxide cyclohex‐2‐ene‐1‐ t ‐butylperoxide.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research