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Two‐dimensional Anhydrous Cadmium(II) Phthalate
Author(s) -
Tang YunZhi,
Qian ShaoSong,
Wang XiSen,
Zhao Hong,
Huang XueFeng,
Li YongHua,
Jiao XingCai,
Xiong RenGen
Publication year - 2004
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200400163
Subject(s) - anhydrous , cadmium , phthalate , chemistry , methanol , hydrolysis , coordination polymer , crystal (programming language) , crystal structure , crystallography , nuclear chemistry , inorganic chemistry , organic chemistry , computer science , programming language
The in situ hydrolysis of phthalyl‐γ‐glutaminyl‐histidine with Cd(ClO 4 ) 2 ·6H 2 O in the presence of water and methanol affords a novel two‐dimensional cadmium coordination polymer, a new phase, anhydrous cadmium(II) phthalate, ( 1 ). The structure was determined by single crystal X‐ray diffraction. Crystal data: P2 1 /c, a = 13.8168(14), b = 7.0351(7), c = 8.2054(8) Å, β = 105.540(2)°, V = 768.43(13) Å 3 , Z = 4, R 1 = 0.0380, wR 2 = 0.1111.