Synthesis and Structure of [Fc(EtO)PS 2 ] ‐  Complexes | Zendy

Gray Ian P. | Zendy; Slawin Alexandra M. Z. | Zendy; Woollins J. Derek | Zendy

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Synthesis and Structure of [Fc(EtO)PS 2 ] ‐ Complexes

Author(s) -

Gray Ian P.,

Slawin Alexandra M. Z.,

Woollins J. Derek

Publication year - 2004

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200400161

Subject(s) - chemistry , crystallography , ion , metal , metal ions in aqueous solution , stereochemistry , organic chemistry

Reaction of Fc(S)PS 2 P(S)Fc with NaOEt gives the non symmetric phosphonodithioato anion [Fc(EtO)PS 2 ] ‐ which can be complexed to a range of metal ions. The group 10 metals (Ni, Pd and Pt) adopt [ML 2 ] complexes with square planar coordination. The first known mercury phosphonodithioate complex is shown to adopt a unique dimeric [M 2 L 4 ] structure. A new structural motif for lead phosphonodithioate complexes is reported consisting of [PbL 2 ] units joined by Pb···S interactions to form distinct dimeric pairs. All new compounds have been characterized spectroscopically and four demonstrative X‐ray structures are reported.

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