The New Polar Intermetallic Compound NaBaBi | Zendy

Hirt Holger | Zendy; Deiseroth HansJörg | Zendy

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The New Polar Intermetallic Compound NaBaBi

Author(s) -

Hirt Holger,

Deiseroth HansJörg

Publication year - 2004

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200400146

Subject(s) - intermetallic , polar , alkali metal , photoelectric effect , materials science , lamellar structure , crystallography , lattice constant , metal , compound semiconductor , chemistry , nanotechnology , metallurgy , epitaxy , physics , optoelectronics , optics , organic chemistry , alloy , layer (electronics) , astronomy , diffraction

Small lamellar air sensitive crystals of NaBaBi with a blue metallic lustre were obtained by direct reaction of the elements. The new polar intermetallic compound, which can formally be described as Na + Ba 2+ Bi 3− crystallizes isotypic to Fe 2 P with lattice constants a = 859.1(1) pm, c = 509.1(1) pm (Z = 3, P $\bar 6$ 2m ). NaBaBi is a small gap semiconductor similar to pnictides of the type A 3 B (A: alkali metal, B: Sb) and thus is a potential candidate for photoelectric applications.

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