One‐dimensional Europium(III) Coordination Polymer Based on 3‐Pyridylacrylic Acid | Zendy

Liu YuJuan | Zendy; Xiong RenGen | Zendy; You XiaoZeng | Zendy; Che ChiMing | Zendy

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One‐dimensional Europium(III) Coordination Polymer Based on 3‐Pyridylacrylic Acid

Author(s) -

Liu YuJuan,

Xiong RenGen,

You XiaoZeng,

Che ChiMing

Publication year - 2004

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200400144

Subject(s) - europium , hydrothermal circulation , ligand (biochemistry) , chemistry , fluorescence , solid state , polymer , coordination polymer , stereochemistry , polymer chemistry , inorganic chemistry , organic chemistry , ion , chemical engineering , biochemistry , receptor , physics , quantum mechanics , engineering

Under hydrothermal conditions, the reaction of racemic 3‐pyridyl‐3‐aminopropionic acid (rac‐HPAPA) with Eu(ClO 4 ) 3 · 6H 2 O affords a 1‐D chain complex, [Eu(3‐PYA) 3 (H 2 O)] n ( 1 ) (3‐PYA=3‐pyridylacrylate), which represents an example of neutral 1‐D coordination polymeric material based on 3‐HPYA (HPYA= pyridylacrylic acid) ligand with strong red fluorescent emission in the solid state.

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