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[Co II Cu I 2 (Im) 4 ] ;∞ : A Layered Bimetallic Imidazolate Polymer, the First Hybridized Cobalt(II) Imidazolate
Author(s) -
Tian YunQi,
Xu HaiJun,
Li YiZhi,
You XiaoZeng
Publication year - 2004
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200400111
Subject(s) - bimetallic strip , imidazolate , cobalt , tetragonal crystal system , crystallography , materials science , zeolitic imidazolate framework , polymer , metal , crystal structure , inorganic chemistry , chemistry , metal organic framework , metallurgy , adsorption , composite material
A 2D grid‐shaped bimetallic imidazolate polymer [Co II Cu I 2 (Im) 4 ] ;∞ ( 1 ) was solvothermally synthesized and characterized with single crystal X‐ray analysis: tetragonal space group P $\bar 4$ 2 1 /c (No.114), a = b = 10.9513(15) Å, c = 6.3063(13) Å, V = 756.3(2) Å 3 . This is the first cobalt(II) imidazolate polymer hybridized with other transition metals.