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[PbAsSi i Pr 3 ] 6 — the First Structurally Characterized Compound with Chemical Bonds between Lead and Arsenic (Z. anorg. allg. Chem. 2004, 630, 3, 345)
Author(s) -
von Hänisch C.,
Nikolova D.
Publication year - 2004
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200400075
Subject(s) - arsenic , crystallography , lead compound , chemistry , crystal (programming language) , crystal structure , stereochemistry , organic chemistry , computer science , biochemistry , in vitro , programming language
The authors of the Short Communication “[PbAsSi i Pr 3 ] 6 — the First Structurally Characterized Compound with Chemical Bonds between Lead and Arsenic” (C. von Hänisch, D. Nikolova, Z. Anorg. Allg. Chem. 2004 , 630 , 345—346) overlooked the quaternary phase K 8 NbPbAs 5 , published by Gascoin und Sevov [1]. Its crystal structure reveals the presence of [NbPbAs 5 ] 8— anions. Therefore this is the first structurally characterized compound with bonds between lead and arsenic. Nevertheless, [PbAsSi i Pr 3 ] 6 remains the sole example of a molecular compound, characterized by single‐crystal X‐ray crystallography, containing such Pb—As bonds and organic substituents. The authors apologize for their oversight. See original Z. anorg. allg. Chem. 2004, 630, 3, 345