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The Stereospecific Substitution of the Xenon Atom in cis ‐Perfluoroalk‐1‐enylxenon( II ) Salts by Hydrogen, Halogens, and the Phenyl Group
Author(s) -
Frohn HermannJosef,
Bardin Vadim V.
Publication year - 2004
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200400056
Subject(s) - propionitrile , halogen , chemistry , stereospecificity , bromine , iodide , medicinal chemistry , benzene , halide , hydrogen iodide , bromide , group (periodic table) , iodine , hydrogen atom , atom (system on chip) , alkyl , organic chemistry , acetonitrile , catalysis , computer science , embedded system
The substitution of the xenon atom in reactions of [ cis ‐C n F 2n+1 CF=CFXe][Y] salts with benzene, iodide, and bromide anions in propionitrile solution by the phenyl group, or iodine, and bromine atoms, respectively, occurred stereospecifically. When a propionitrile solution of [ cis ‐C 2 F 5 CF=CFXe][AsF 6 ] was kept at —40 °C without an additional reactant, the fluoroalkene cis ‐C 2 F 5 CF=CFH was the only isomer obtained.