[Ph 2 P(O)CH 2 Im][F 3 B(μ‐OH)BF 3 ]. Erste strukturanalytische Charakterisierung des Hexafluoro(μ‐hydroxo)diborat‐Ions [1] | Zendy

Kuhn Norbert | Zendy; Göhner Martin | Zendy; Steimann Manfred | Zendy

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[Ph 2 P(O)CH 2 Im][F 3 B(μ‐OH)BF 3 ]. Erste strukturanalytische Charakterisierung des Hexafluoro(μ‐hydroxo)diborat‐Ions [1]

Author(s) -

Kuhn Norbert,

Göhner Martin,

Steimann Manfred

Publication year - 2003

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200390100

Subject(s) - chemistry , ion , crystal structure , hydrolysis , hydrogen bond , salt (chemistry) , crystallography , stereochemistry , inorganic chemistry , molecule , organic chemistry

[Ph 2 P(O)CH 2 Im][F 3 B(μ‐OH)BF 3 ]. First Structural Characterization of the Hexafluoro(μ‐hydroxo)diborate Ion [1] The hexafluoro(μ‐hydroxo)diborate ion has been isolated as it's Ph 2 P(O)CH 2 Im salt [Im = 2‐(1, 3, 4, 5‐tetramethylimidazolio)] ( 2 ) through basic hydrolysis of [Ph 2 P(OBF 3 )CH 2 Im]BF 4 ( 1 ). The crystal structure of 2 · CH 2 Cl 2 reveals the presence of ion pairs linked by unsymmetrical O‐H‐O hydrogen bonds.

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