Die Kristallstruktur von wasserfreiem Melaminiumchlorid | Zendy

Jing Haipeng | Zendy; Ströbele Markus | Zendy; Weisser Martina | Zendy; Meyer H.Jürgen | Zendy

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Die Kristallstruktur von wasserfreiem Melaminiumchlorid

Author(s) -

Jing Haipeng,

Ströbele Markus,

Weisser Martina,

Meyer H.Jürgen

Publication year - 2003

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200390060

Subject(s) - chloride , crystal structure , hydrogen bond , crystallography , chemistry , supramolecular chemistry , ion , single crystal , aqueous solution , ammonium chloride , molecule , organic chemistry

Crystal Structure of non‐aqueous Melaminium Chloride Melaminium chloride was obtained as colorless, needle‐shaped, single crystalline material from solid state reactions between melamin and ammonium chloride. The structure of [C 3 N 6 H 7 ]Cl was refined by single crystal X‐ray diffraction: I2/m, Z = 8, a = 852.87(4), b = 1704.4(1) c = 918.44(4) pm and β = 92.165(6)°. The crystal structure contains melaminium ions stacked to columns along [100] and linked via N‐H···N bridges to form bands along [001]. Both of the two distinct chloride ions are stabilized by six hydrogen bonds through distorted trigonal prismatic arrangements of hydrogen atoms to yield a supramolecular structure.

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