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Synthesis and Structures of Potassium Bisdithiocarbamate Salts
Author(s) -
Cook David A.,
Coles Simon J.,
Hursthouse Michael B.,
Price Daniel J.
Publication year - 2003
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200390030
Subject(s) - potassium , lamellar structure , derivative (finance) , chemistry , alkyl , isopropyl , solid state , crystal structure , stereochemistry , crystallography , medicinal chemistry , organic chemistry , financial economics , economics
Two structurally related dipotassium bisdithiocarbamate salts: K 2 [(S 2 CNRCH 2 ) 2 ](EtOH) 2 ; R = Me, i ‐Pr, were synthesised from the corresponding diamines. X‐ray structure determinations were performed on single crystals grown from ethanolic solutions. The different alkyl substituents have a profound affect upon the solid‐state structures, with the methyl derivative possessing a complex a 3‐D network and the isopropyl derivative a 2‐D lamellar structure.