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A Stable Carbene Phosphenic Chloride Complex: First Structural Characterization of a PO 2 Cl Base Adduct [1]
Author(s) -
Kuhn Norbert,
Ströbele Markus,
Walker Michael
Publication year - 2003
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200390026
Subject(s) - adduct , carbene , hydrolysis , chemistry , chloride , base (topology) , medicinal chemistry , polymer chemistry , organic chemistry , catalysis , mathematical analysis , mathematics
The phosphenic chloride adduct Im—PO 2 Cl ( 4 , Im = 2, 3‐dihydro‐1, 3‐diisopropyl‐4, 5‐dimethylimidazol‐2‐ylidene) was prepared by partial hydrolysis of [Im—POCl 2 ]Cl ( 5 ) and characterized by X‐ray structure analysis.