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Synthesis and Molecular Structure of [ n ‐Bu 2 (F)SnOSn(F) t ‐Bu 2 ] 2 — an Unsymmetrically Substituted Tetraorganodistannoxane
Author(s) -
Beckmann Jens,
Dakternieks Dainis,
Duthie Andrew,
Jurkschat Klaus,
Schürmann Markus
Publication year - 2003
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200390023
Subject(s) - nuclear magnetic resonance spectroscopy , spectroscopy , crystallography , solid state , chemistry , mass spectrometry , diffraction , stereochemistry , physics , chromatography , quantum mechanics , optics
The dimeric tetraorganodistannoxane [ n ‐Bu 2 (F)SnOSn(F) t ‐Bu 2 ] 2 ( 1 ) was prepared by the reaction of ( t ‐Bu 2 SnO) 3 with n ‐Bu 2 SnF 2 and characterized in solution by multinuclear NMR spectroscopy and ESI MS spectrometry and in the solid state by 119 Sn MAS NMR spectroscopy and single crystal X‐ray diffraction.