Synthesis and Crystal Structure of a new O, N Lithium Coordination Polymer | Zendy

Ghassemzadeh Mitra | Zendy; Heravi Majid M. | Zendy; HekmatShoar Rahim | Zendy; Neumüller Bernhard | Zendy

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Synthesis and Crystal Structure of a new O, N Lithium Coordination Polymer

Author(s) -

Ghassemzadeh Mitra,

Heravi Majid M.,

HekmatShoar Rahim,

Neumüller Bernhard

Publication year - 2003

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200300300

Subject(s) - dimethoxyethane , crystal structure , coordination polymer , lithium (medication) , elemental analysis , chemistry , polyphosphazene , crystallography , mass spectrometry , inorganic chemistry , polymer , organic chemistry , medicine , electrode , chromatography , electrolyte , endocrinology

The reaction of 4‐Amino‐6‐methyl‐1, 2, 4‐triazine‐3(2H)‐thione‐5‐one (HAMTTO) with n ‐butyl lithium in dimethoxyethane (DME) gives the complex [Li(DME)(AMTTO)] ( 1 ). 1 was characterized by elemental analysis, IR‐ and mass‐spectrometry and an X‐ray structure analysis [space group P2 1 /n, Z = 4, lattice dimensions at —80 °C: a = 867.6(1), b = 1721.5(2), c = 931.8(1) pm, β = 112.81(1)°, R 1 = 0.0315. The complex is a coordination polymer along [001] with a zig‐zag arrangement.

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