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Synthesis and Crystal Structure of a new O, N Lithium Coordination Polymer
Author(s) -
Ghassemzadeh Mitra,
Heravi Majid M.,
HekmatShoar Rahim,
Neumüller Bernhard
Publication year - 2003
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200300300
Subject(s) - dimethoxyethane , crystal structure , coordination polymer , lithium (medication) , elemental analysis , chemistry , polyphosphazene , crystallography , mass spectrometry , inorganic chemistry , polymer , organic chemistry , medicine , electrode , chromatography , electrolyte , endocrinology
The reaction of 4‐Amino‐6‐methyl‐1, 2, 4‐triazine‐3(2H)‐thione‐5‐one (HAMTTO) with n ‐butyl lithium in dimethoxyethane (DME) gives the complex [Li(DME)(AMTTO)] ( 1 ). 1 was characterized by elemental analysis, IR‐ and mass‐spectrometry and an X‐ray structure analysis [space group P2 1 /n, Z = 4, lattice dimensions at —80 °C: a = 867.6(1), b = 1721.5(2), c = 931.8(1) pm, β = 112.81(1)°, R 1 = 0.0315. The complex is a coordination polymer along [001] with a zig‐zag arrangement.