Anhydrous Mercurous Chlorate, Hg 2 (ClO 3 ) 2 | Zendy

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Anhydrous Mercurous Chlorate, Hg 2 (ClO 3 ) 2

Author(s) -

Göbbels Dirk,

Meyer Gerd

Publication year - 2003

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200300299

Subject(s) - anhydrous , chlorate , chemistry , monoclinic crystal system , mercury (programming language) , inorganic chemistry , crystal structure , oxide , nuclear chemistry , crystallography , organic chemistry , computer science , programming language

Colourless single crystals of the anhydrous mercurous chlorate were grown from a solution of mercuric oxide (HgO) in chloric acid (HClO 3 ) in the presence of elemental mercury. The crystal structure (monoclinic, P2 1 /n, Z = 4, a = 816.59(12), b = 641.02(5), c = 1290.3(2) pm, β = 97.506(12)°, R(all) = 0.0317) contains trans‐O 2 ClO‐Hg‐Hg‐OClO 2 molecules with a Hg‐Hg distance of 251.03(4) pm, Hg‐O (bond) distances of 218 and 224 pm and Hg‐Hg‐O angles of 177 and 165°, respectively.

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