Synthesis and Crystal Structure of [Fe(Cp) 2 ] 3 (Bi 2 Cl 9 )·thf | Zendy

Savilov Serguei | Zendy; Kloo Lars | Zendy; Kuznetsov Alexei | Zendy; Popovkin Boris | Zendy; Fischer Andreas | Zendy

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Synthesis and Crystal Structure of [Fe(Cp) 2 ] 3 (Bi 2 Cl 9 )·thf

Author(s) -

Savilov Serguei,

Kloo Lars,

Kuznetsov Alexei,

Popovkin Boris,

Fischer Andreas

Publication year - 2003

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200300289

Subject(s) - orthorhombic crystal system , crystallography , ferrocene , crystal structure , ion , chemistry , molecule , slow cooling , unit (ring theory) , formula unit , stereochemistry , materials science , mathematics , organic chemistry , electrochemistry , mathematics education , electrode , metallurgy

Single crystals of [Fe(Cp) 2 ] 3 (Bi 2 Cl 9 )·thf were obtained from a thf solution containing ferrocene and BiCl 3 . The structure shows disorder at room temperature which disappears upon cooling, coupled with a decrease in symmetry. The title compound crystallizes in the orthorhombic space group P 2 1 2 1 2 1 [a = 1698.64(2), b = 2318.69(3), c = 1085.66(2) pm] with three ferrocenium ions, one nonachlorodibismutate ion and one molecule of thf in the asymmetric unit.

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