Halogen‐Halogen‐Wechselwirkungen im Kristall von 2 ImIBr · Br‐CF 2 CF 2 ‐I (Im = 1, 3‐Diisopropyl‐4, 5‐dimethylimidazoly [1] | Zendy

Kuhn Norbert | Zendy; AbuRayyan Ahmed | Zendy; Steimann Manfred | Zendy

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Halogen‐Halogen‐Wechselwirkungen im Kristall von 2 ImIBr · Br‐CF 2 CF 2 ‐I (Im = 1, 3‐Diisopropyl‐4, 5‐dimethylimidazoly [1]

Author(s) -

Kuhn Norbert,

AbuRayyan Ahmed,

Steimann Manfred

Publication year - 2003

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200300261

Subject(s) - halogen , chemistry , adduct , crystal structure , medicinal chemistry , crystal (programming language) , crystallography , stereochemistry , organic chemistry , alkyl , computer science , programming language

Interactions between Halogen Atoms in the Crystal of 2 ImIBr · Br‐CF 2 CF 2 ‐I (Im = 1, 3‐Diisopropyl‐4, 5‐dimethylimidazoly[1] 2, 3‐Dihydro‐1, 3‐diisopropyl‐4, 5‐dimethylimidazol‐2‐ylidene ( 3 , Im) reacts with Br‐CF 2 CF 2 ‐I to give the adduct 2 Im‐I‐Br · Br‐CF 2 CF 2 ‐I ( 5 ). The crystal structure analysis of 5 exhibits near linear C‐I‐Br interactions in addition to short Br‐Br and Br‐I contacts to the Br‐CF 2 CF 2 ‐I fragment.

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