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A Merrifield Resin Functionalized with Molybdenum Peroxo Complexes: Synthesis and Catalytic Properties
Author(s) -
Hinner Marlon J.,
Grosche Manja,
Herdtweck Eberhardt,
Thiel Werner R.
Publication year - 2003
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200300216
Subject(s) - polystyrene , molybdenum , catalysis , cyclooctene , deprotonation , polymer chemistry , pyridine , chemistry , ligand (biochemistry) , chelation , polymer , organic chemistry , ion , biochemistry , receptor
CH 2 Cl functionalized polystyrene (Merrifield resin) was reacted with deprotonated 2‐(3‐pyrazolyl)pyridine to give a polymer bound chelate ligand system, which could be co‐ordinated to oxodiperoxo molybdenum(VI) units. The resulting heterogenized catalyst was investigated for its activity in the epoxidation of cyclooctene.