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Zur Synthese von Na 3 FeO 3 , einem ternären Oxoferrat(III) mit Kettenstruktur
Author(s) -
Sobotka Bettina M.,
Möller Angela
Publication year - 2003
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200300206
Subject(s) - crystallography , ternary operation , crystal structure , chemistry , metal , single crystal , materials science , organic chemistry , computer science , programming language
Synthesis of Na 3 FeO 3 , a Ternary Oxoferrate(III) with a Chain Structure Na 3 FeO 3 has been obtained from a redox reaction between CdO and iron metal in the presence of Na 2 O and Na 2 CO 3 at 650 °C as amber colored transparent single crystals. The crystal structure determination (IPDS data: P2 1 /n, a = 579.9(1) pm, b = 1265.9(2) pm, c = 582.8(1) pm, β = 116.02(2)°, Z = 4, R all = 0.0576) reveals the presence of ∞ 1 [FeO 2 O 2/2 ] zig‐zag‐chains.