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Reaktionen von Cyclostibanen (RSb) n [R = (Me 3 Si) 2 CH, n = 3; Me 3 CCH 2 , n = 4, 5] mit den Übergangsmetallcarbonyl‐Komplexen [W(CO) 5 (thf)], [Cp x Mn(CO) 2 (thf)], [Cp x Cr(CO) 3 ] 2 und [Co 2 (CO) 8 ]; Cp x = MeC 5 H 4
Author(s) -
Balázs G.,
Breunig H. J.,
Lork E.
Publication year - 2003
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - German
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200300171
Subject(s) - tetrahydrofuran , chemistry , medicinal chemistry , stereochemistry , organic chemistry , solvent
(RSb) 3 [R = (Me 3 Si) 2 CH] reagiert mit [W(CO) 5 (thf)], [Cp x Mn(CO) 2 (thf)] oder [Co 2 (CO) 8 ] zu [(RSb) 3 W(CO) 5 ] ( 1 ), [RSb{Mn(CO) 2 Cp x } 2 ] ( 2 ) oder [RSbCo(CO) 3 ] 2 ( 3 ). Die Reaktion von (R′Sb) n (n = 4, 5; R′ = Me 3 CCH 2 ) mit [Cp x Cr(CO) 3 ] 2 führt zu [(R′Sb) 4 {Cr(CO) 2 Cp x } 2 ] ( 4 ); Cp x = MeC 5 H 4 , thf = Tetrahydrofuran.

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