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Crystal Structure of LiClO 4
Author(s) -
Wickleder Mathias S.
Publication year - 2003
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200300114
Subject(s) - octahedron , perchlorate , crystallography , crystal structure , lithium (medication) , ion , lithium perchlorate , chemistry , inorganic chemistry , materials science , electrochemistry , electrode , organic chemistry , medicine , endocrinology
Single crystals of LiClO 4 were obtained during attempts to prepare lithium containing rare earth perchlorates from a lithium perchlorate melt. In the crystal structure of LiClO 4 (ortho‐rhombic, Pnma , Z =4, a = 865.7(1), b = 691.29(9) pm, c = 483.23(6), R all = 0.0273) the Li + ions are in distorted octahedral coordination of oxygen atoms. The octahedra are linked via common edges to chains according to 1 [LiO 2/1 O 4/2 ] which run in the [010] direction. The perchlorate ions are almost ideal tetrahedra.
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