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Crystal Structure of a Ce III /Fe III Heterobimetallic Complex
Author(s) -
Deacon Glen B.,
Forsyth Craig M.,
Forsyth Maria
Publication year - 2003
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200300089
Subject(s) - moiety , crystallography , glycolic acid , carboxylate , crystal structure , chemistry , oxide , rare earth , stereochemistry , mineralogy , geology , organic chemistry , lactic acid , paleontology , bacteria
A central μ 3 —O moiety linking two Fe III and one Ce III sites supported by two distinct heterometallic carboxylate bridging modes features in self‐assembled [CeFe 2 (bpy) 2 (μ 3 —O)(μ—L) 2 (μ—LH) 2 (LH)(H 2 O) 2 ]·0.5(bpy)·7H 2 O ( 1 ) (LH 2 = glycolic acid), and the structure models potential bonding modes of the Rare Earth corrosion inhibitor Ce(glycolate) 3 to iron or iron oxide.