Premium
Synthese und Kristallstruktur von [(Me 3 Si) 2 BiCu(PMe 3 ) 3 ], dem ersten Komplex mit einer Bismut—Kupfer‐Bindung
Author(s) -
Fenske Dieter,
Rothenberger Alexander,
Wieber Stephan
Publication year - 2003
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200300062
Subject(s) - phosphine , crystal structure , chemistry , bismuth , crystallography , catalysis , organic chemistry
Synthesis and Crystal Structure of [(Me 3 Si) 2 BiCu(PMe 3 ) 3 ] — the First Complex with a Bismuth—Copper Bond The reaction of CuO t Bu with PMe 3 and Bi(SiMe 3 ) 3 in hexane yields the phosphine‐stabilized complex [(Me 3 Si) 2 Bi‐Cu( PMe 3 ) 3 ]. This synthesis gave rise to the first binuclear Bi—Cu compound to be structurally characterized by X‐ray crystallography.