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Polyol‐Metall‐Komplexe. 27. Bis‐diolato‐antimonate( III ) mit Guanosin als Diol
Author(s) -
Klüfers Peter,
Mayer Peter
Publication year - 1997
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19976231003
Subject(s) - antimonate , chemistry , organic chemistry , antimony
Polyol Metal Complexes. 27. Bis‐Diolato Antimonates( III ) with Guanosine as the Diol The complex anions of K 3 [Sb III (Guo1,2′,3′H −3 ) 2 ] · 10 H 2 O ( 1 ) and [Co(NH 3 ) 6 ][Sb III (Guo1,2′,3′H −3 ) 2 ] · 9 H 2 O ( 2 ) are four‐coordinate homoleptic bis(diolato)antimonate( III ) species. The guanosine trianions act as carbohydrate ligands through their cis ‐furanoidic ribosyl moiety, thus forming no nucleobase–metal bonds.