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Synthesis, characterization, and structures of 1‐(9‐Fluorenyl)‐germatrane and 1‐(Phenylacetylenyl)germatrane
Author(s) -
Zaitseva Galina S.,
Karlov Sergei S.,
Churakov Andrei V.,
Howard Judith A. K.,
Avtomonov Evgeni V.,
Lorberth JÖRg
Publication year - 1997
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19976230723
Subject(s) - mass spectrometry , chemistry , crystal structure , elemental analysis , stereochemistry , nuclear magnetic resonance spectroscopy , crystallography , organic chemistry , chromatography
Syntheses of the title compounds, viz . N(CH 2 CH 2 O) 3 GeY ( 2 YFluorenyl; 4 YPhCC) by the reaction of X 3 GeY ( 1 YFluorenyl, XBr; 5 YPhCC, XCl) with N(CH 2 CH 2 OSnR 3 ) 3 ( 3 REt; 6 RBu) are reported including the preparation of the new compound 1 . Identity and structures were established by elemental analyses, 1 H and 13 C NMR spectroscopy. 2 and 4 were characterized by mass spectrometry. Single crystal structures of 1 , 2 and 4 were determined by X‐ray diffraction methods.
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