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1,3,2‐Diazasiloles by Silylene Addition to Trifluoroacetonitrile
Author(s) -
Weidenbruch Manfred,
Will Peter,
Peters Karl
Publication year - 1996
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19966221102
Subject(s) - silylene , steric effects , ring (chemistry) , derivative (finance) , chemistry , constitution , stereochemistry , medicinal chemistry , organic chemistry , silicon , political science , law , business , finance
The addition reactions of the sterically encumbered silylenes R 2 Si:, R = 2,4,6‐Me 3 C 6 H 2 or t Bu, to trifluoroacetonitrile furnish the correspondingly substituted 1,3,2‐diazasiloles. The constitution of this five‐membered ring system was confirmed by spectroscopic data and, in the case of the dimesityl derivative, by an X‐ray crystal structure analysis.