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Reactions of Pentafluorobenzenesulfanylamines (C 6 F 5 S) n NH 3–n , n = 1, 2, 3 and the Structure of (C 6 F 5 S) 3 N
Author(s) -
Biehl Alexander,
Boese Roland,
Haas Alois,
Klare Christiane,
Peach Michael
Publication year - 1996
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19966220726
Subject(s) - crystal structure , crystallography , mass spectrum , chemistry , bond length , x ray crystallography , mass spectrometry , physics , diffraction , chromatography , optics
The crystal structure of (C 6 F 5 S) 3 N has been examined. The compounds (C 6 F 5 S) 2 NX, X = SiMe 3 and ½ Hg have been prepared from (C 6 F 5 S) 2 NH and characterised. In a number of other reactions, such as oxidation and irradiation, the SN bond in (C 6 F 5 S) 2 NH was readily fractured, forming the disulfide, (C 6 F 5 S) 2 . The compound (C 6 F 5 S) 3 N has been found to be unreactive. Details of the mass and 13 C NMR spectra of (C 6 F 5 S) n NH 3–n , n = 1, 2, 3 are reported.