Ba 4 [WN 4 ]Cl 2 : The first nitridotungstate(VI) chloride | Zendy

Wachsmann Ch. | Zendy; Jacobs H. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Ba 4 [WN 4 ]Cl 2 : The first nitridotungstate(VI) chloride

Author(s) -

Wachsmann Ch.,

Jacobs H.

Publication year - 1996

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19966220523

Subject(s) - monoclinic crystal system , chloride , crystal structure , crystallography , chemistry , crystal (programming language) , organic chemistry , computer science , programming language

Transparent yellow crystals of Ba 4 [WN 4 ]Cl 2 were grown at 850°C by the reaction of Ba(NH 2 ) 2 with W in a KCl melt under flowing nitrogen. The compound crystallizes monoclinic in P2 1 /m and Z = 2 with the cell parameters a = 8.447(4) Å, b = 6.143(2) Å, c = 10.727(6) Å and β = 99.04(4)°. The crystal structure contains isolated anions [WN 4 ] 6− and Cl − . It is the first nitridotungstate(VI) chloride reported so far.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research