Crystal and Molecular Structure of Bis(η 5 ‐methylcyclopentadienyl)titana(IV)‐cyclohexasulfane Ti(η 5 ‐C 5 H 4 CH 3 ) 2 S 5 | Zendy

Klouras Nikolaos | Zendy; Demakopoulos Ioannis | Zendy; Terzis Aris | Zendy; Raptopoulou Caterina P. | Zendy

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Crystal and Molecular Structure of Bis(η 5 ‐methylcyclopentadienyl)titana(IV)‐cyclohexasulfane Ti(η 5 ‐C 5 H 4 CH 3 ) 2 S 5

Author(s) -

Klouras Nikolaos,

Demakopoulos Ioannis,

Terzis Aris,

Raptopoulou Caterina P.

Publication year - 1995

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19956210121

Subject(s) - monoclinic crystal system , crystallography , crystal structure , cyclohexane , ring (chemistry) , crystal (programming language) , x ray crystallography , space group , titanium , molecular geometry , chemistry , molecule , diffraction , physics , organic chemistry , computer science , optics , programming language

The crystal and molecular structure of Ti( n 5 ‐C 5 H 4 CH 3 ) 2 S 5 has been determined by X‐ray diffraction studies. The substance crystallizes in the monoclinic crystal system [a = 6.8642(5), b = 16.507(1), c = 13.074(1) Å, β = 82.407(3)°, space group P2 1 /n, Z = 4]. The geometry about the titanium atom is a distorted tetrahedron, with a (centroid)‐Ti‐(centroid) angle of 131.29° and a STiS angle of 93.38°. The six‐membered ring TiS 5 has a cyclohexane‐like chair configuration. The structural results are compared to those for similar type titanium complexes.

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