Synthesis and Characterization of (Z)‐1‐[2‐(Triarylstannyl)vinyl]‐1‐Cyclohexanols and their Arylhalostannyl Derivatives | Zendy

Xin Fu Fang | Zendy; Lin Shan Xi | Zendy; Jie Fu Yu | Zendy; Pan Huade | Zendy; Mahieu Bernard | Zendy; Gielen Marcel | Zendy; Kayser François | Zendy; Willem Rudolph | Zendy

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Synthesis and Characterization of (Z)‐1‐[2‐(Triarylstannyl)vinyl]‐1‐Cyclohexanols and their Arylhalostannyl Derivatives

Author(s) -

Xin Fu Fang,

Lin Shan Xi,

Jie Fu Yu,

Pan Huade,

Mahieu Bernard,

Gielen Marcel,

Kayser François,

Willem Rudolph

Publication year - 1994

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19946200609

Subject(s) - cyclohexanol , chemistry , halogen , hydride , medicinal chemistry , organic chemistry , catalysis , hydrogen , alkyl

1‐Ethynyl‐1‐cyclohexanol reacts with a triaryltin hydride Ar 3 SnH (Ar = phenyl, p‐tolyl) and generates the corresponding (Z)‐1‐[2‐(triarylstannyl)vinyl]‐1‐cyclohexanol. The product obtained reacts with one or two equivalents of halogen (ICl or I 2 ) to form the associated (Z)‐1‐[2‐(diarylhalostannyl)‐vinyl]‐1‐cyclohexanol or (Z)‐1‐[2‐(aryldihalostannyl)vinyl]‐1‐cyclohexanol, respectively. All compounds were characterized by elemental analysis, 1 H, 13 C, 119 Sn NMR and Mössbauer spectroscopy.

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