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Synthesis and Characterization of (Z)‐1‐[2‐(Triarylstannyl)vinyl]‐1‐Cyclohexanols and their Arylhalostannyl Derivatives
Author(s) -
Xin Fu Fang,
Lin Shan Xi,
Jie Fu Yu,
Pan Huade,
Mahieu Bernard,
Gielen Marcel,
Kayser François,
Willem Rudolph
Publication year - 1994
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19946200609
Subject(s) - cyclohexanol , chemistry , halogen , hydride , medicinal chemistry , organic chemistry , catalysis , hydrogen , alkyl
1‐Ethynyl‐1‐cyclohexanol reacts with a triaryltin hydride Ar 3 SnH (Ar = phenyl, p‐tolyl) and generates the corresponding (Z)‐1‐[2‐(triarylstannyl)vinyl]‐1‐cyclohexanol. The product obtained reacts with one or two equivalents of halogen (ICl or I 2 ) to form the associated (Z)‐1‐[2‐(diarylhalostannyl)‐vinyl]‐1‐cyclohexanol or (Z)‐1‐[2‐(aryldihalostannyl)vinyl]‐1‐cyclohexanol, respectively. All compounds were characterized by elemental analysis, 1 H, 13 C, 119 Sn NMR and Mössbauer spectroscopy.