Premium
Molecular and crystal structure of Bis(η 5 ‐cyclopentadienyl)titanium(IV) Dibromide, Ti(η 5 ‐C 5 H 5 ) 2 Br 2
Author(s) -
Klouras N.,
Nastopoulos V.,
Demakopoulos I.,
Leban I.
Publication year - 1993
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19936191117
Subject(s) - triclinic crystal system , cyclopentadienyl complex , crystallography , crystal structure , molecule , titanium , chemistry , crystal (programming language) , x ray crystallography , space group , diffraction , physics , biochemistry , organic chemistry , optics , computer science , programming language , catalysis
Abstract The crystal and molecular structure of Bis(η 5 ‐cyclopentadienyl)titanium(IV) dibromide, Ti(η 5 −C 5 H 5 ) 2 Br 2 , has been investigated by an X‐ray structure determination. Crystal data: triclinic, a = 7.872(5), b = 11.807(5), c = 12.310(3) Å, α = 107.62(3), β = 100.83(4), γ = 90.69(4)°, V = 1 068(14) Å 3 , T = 293, space group P 1 , Z = 4 (there are two crystallographically independent molecules in the asymmetric unit cell and their conformations are similar). Final R and R w values are 0.068 and 0.073, respectively. The structural results are compared to those for similar type molecules.