Vapours above molten mixtures of CuCl 2 KClLaCl 3 | Zendy

Berg Å. | Zendy; Sørlie M. | Zendy; Øye Harald A. | Zendy

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Vapours above molten mixtures of CuCl 2 KClLaCl 3

Author(s) -

Berg Å.,

Sørlie M.,

Øye Harald A.

Publication year - 1990

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.19905830117

Subject(s) - vapours , chlorine , vapor pressure , chemistry , chlorine atom , inorganic chemistry , lewis acids and bases , molar ratio , phase (matter) , analytical chemistry (journal) , base (topology) , medicinal chemistry , organic chemistry , neuroscience , mathematical analysis , mathematics , biology , catalysis

The vapour phase above mixtures of CuCl 2 KClLaCl 3 has been studied. The vapour species CuCl 2 , Cu 3 Cl 3 , Cl 2 have been identified and there is an indication of the presence of the species Cu 2 Cl 4 , KCuCl 3 as well as a CuLaCl complex. A maximum in the chlorine pressure is found for the molar ratio Cu/K/La ≈ 50/35/15. The variation of the chlorine pressure is explained from a Lewis acid‐base theory.

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