Premium
Synthesis, infrared and 121 Sb Mössbauer spectra of some Antimony(III) Thiocyanate Complexes
Author(s) -
Bertazzi N.,
Alonzo G.
Publication year - 1989
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19895750125
Subject(s) - antimony , thiocyanate , chemistry , adduct , infrared spectroscopy , infrared , nitrogen , mössbauer spectroscopy , crystallography , inorganic chemistry , organic chemistry , physics , optics
The first isolation of an antimony(III) thiocyanate complex salt, [(CH 3 ) 4 N][Sb(CNS) 4 ] ( I ), and of two adducts of the Sb(CNS) 3 formal unit with potentially tridentate nitrogen donors, Sb(CNS) 3 tpta ( II ) and [Sb(CNS) 3 ] 3 (dqp) 2 ( III ), is described. In these derivatives, infrared and Mössbauer spectral data are essentially indicating the predominant presence of N‐bonded thiocyanate. For complex I , the occurrence also of groups bridging through the nitrogen atom is advanced.