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Nitrosyl rhenium complexes: Syntheses, properties, and structures of acetylacetonato derivatives
Author(s) -
Mitra T.,
Sen S.,
Sen B. K.,
Bandyopadhyay P.
Publication year - 1987
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19875480524
Subject(s) - acetylacetone , rhenium , chemistry , medicinal chemistry , inorganic chemistry
Some new complexes of rhenium containing monocoordinating acetylacetone viz. [Re(NO)(acac) 2 (Cl)H 2 O], Re(NO)(acac) 3 (acacH)(H 2 O) 2 have been synthesized by reacting acetylacetone with either Re(NO)Cl 3 · H 2 O or Re(NO)(OH) 3 · H 2 O. The preparation of [Re(NO)(py)(acac) 2 (Cl) · H 2 O], [Re(NO)(acac)(OH)(Cl) · H 2 O], [Re 2 (NO) 2 (acacH) 3 (acac) 2 · Cl 4 ], [Re(NO)(acac) 2 (OH) · H 2 O] · 2 H 2 O have also been described. These complexes were characterized through their elemental analyses, u.v., vis, i.r., 1 Hn.m.r., magnetic, and conductance data.