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X‐Ray Photoelectron Spectroscopy of Palladium Fluorides
Author(s) -
Tressaud A.,
Khairoun S.,
Touhara H.,
Watanabe N.
Publication year - 1986
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19865400932
Subject(s) - palladium , x ray photoelectron spectroscopy , oxidation state , binding energy , octahedron , x ray , fluorine , chemistry , crystallography , spectral line , inorganic chemistry , metal , atomic physics , nuclear magnetic resonance , catalysis , crystal structure , physics , organic chemistry , astronomy , quantum mechanics
X‐ray photoelectron spectra of several Palladium fluorine compounds have been investigated. In all these phases Palladium atoms have a more or less distorted octahedral coordination. Satellite Structures generally occur in Pd 3d 3/2 and Pd 3d 5/2 levels and broad F 1s peaks are observed. Shifts in binding energies can be correlated with Palladium oxidation State and covalency. XPS results clearly confirm the unusual +III oxidation State of Palladium in NaPdF 4 , Na 3 PdF 6 , K 3 PdF 6 , and K 2 NaPdF 6 .